Enchanted emerald bolts are mithril bolts tipped with enchanted emerald. Emerald bolts can be enchanted through the spell Enchant Crossbow Bolt (Emerald) by a player with level 27 Magic. The spell enchants 10 emerald bolts at a time.
Enchanted emerald bolts are enchanted with the Magical Poison enchantment. This makes the bolts count as being poisoned with extra-extra-extra strong poison (5 damage, even higher than p++ projectiles with a initial damage of 4), although they have an increased chance of poisoning their opponent.